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Class 12 Chemistry — Chapter 4: The d- and f-Block Elements

96 practice questions · 32 Easy · 32 Medium · 32 Hard

Practise Class 12 Chemistry Chapter 4, "The d- and f-Block Elements", with 96 NCERT-aligned multiple-choice questions. The set is split into 32 Easy, 32 Medium and 32 Hard questions, so you can warm up on the fundamentals and then push into the exam-level problems that separate top scorers in CBSE Board exams, JEE Main, JEE Advanced and NEET UG.

"The d- and f-Block Elements" is one of the chapters where reactions, named concepts, and balanced numerical work really pays off. Each MCQ on this chapter is timed and uses exam-grade marking (+2 correct, −1 wrong, 0 skipped), training the same accuracy-under-pressure that real papers demand. Every question carries a short explanation, so a wrong answer becomes a quick lesson rather than a dead end — the fastest way to close gaps before a test.

Use this chapter as targeted revision: attempt the Easy set first to confirm your basics on The d- and f-Block Elements, then move to Medium and Hard to test application and problem-solving. Your accuracy, streaks and XP save automatically, and the chapter feeds into your overall Class 12 Chemistry mastery score. A few sample questions are shown below; sign in free to practise all 96.

Key concepts: The d- and f-Block Elements (Class 12 Chemistry)

This chapter covers the transition (d-block) and inner-transition (f-block) elements — their electronic configurations, characteristic properties, and important compounds.

d-block elements
Transition metals with partly filled d-orbitals; show variable oxidation states, coloured ions, catalytic activity and form complexes.
Variable oxidation states
Arise because the (n−1)d and ns electrons have similar energies and can both participate in bonding.
Coloured ions & magnetism
Colour is due to d–d electronic transitions; many ions are paramagnetic due to unpaired d-electrons (spin-only formula).
Lanthanoid contraction
A steady decrease in size across the lanthanoids due to poor shielding by 4f electrons; affects the properties of later d-block elements.
Important compounds
Potassium dichromate (K₂Cr₂O₇) and potassium permanganate (KMnO₄) are strong oxidising agents with well-known preparations.

Key formulas — The d- and f-Block Elements

Spin-only magnetic moment
μ = √[n(n + 2)] BM (n = unpaired electrons)

💡 Exam tips for The d- and f-Block Elements

  • Use μ = √[n(n+2)] to estimate the number of unpaired electrons from the magnetic moment.
  • Lanthanoid contraction explains why 4d and 5d elements of a group have nearly the same size.

Sample questions

Q1Easy

d-block elements have last electron in:

A.d-orbital✓ correct
B.s-orbital
C.p-orbital
D.f-orbital
Why

Penultimate shell d-orbital.

Q2Medium

Transition metals show:

A.Variable oxidation states✓ correct
B.Fixed +1 only
C.Only +2
D.None
Why

Close energies of (n−1)d and ns electrons.

Q3Hard

Why are many transition metals good catalysts?

A.Variable oxidation states + ability to adsorb reactants✓ correct
B.Low density
C.Soft texture
D.Coloured ions
Why

Provide alternative reaction pathways.

The d- and f-Block Elements — FAQs

What are the key concepts in Class 12 Chemistry The d- and f-Block Elements?+

This chapter covers the transition (d-block) and inner-transition (f-block) elements — their electronic configurations, characteristic properties, and important compounds. Key ideas include d-block elements, Variable oxidation states, Coloured ions & magnetism, Lanthanoid contraction, Important compounds.

What does Class 12 Chemistry Chapter 4 (The d- and f-Block Elements) cover on XamBaaz?+

It covers 96 NCERT-aligned MCQs on "The d- and f-Block Elements" — 32 Easy, 32 Medium and 32 Hard — each with a timed quiz and an instant explanation, suitable for CBSE Board exams, JEE Main, JEE Advanced and NEET UG.

Are these "The d- and f-Block Elements" questions free to practise?+

Yes — sign in with Google to practise "The d- and f-Block Elements" free. Full unlimited access is ₹999/year (limited-time launch price), with no per-chapter charges.

How should I revise "The d- and f-Block Elements" for the exam?+

Start with the Easy quiz to confirm your fundamentals, then attempt Medium and Hard for application-level practice. Review each explanation, retry the questions you miss, and track your accuracy on this chapter until it is consistently high.

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